NEW SYNTHETIC METHOD OF (Z)-4-ALKENOIC ACIDS USING RING-OPENING REACTION OF (Z)-4-HEXENOLIDE WITH ORGANOCOPPER REAGENT

DOI: 10.1246/cl.1984.1795

Source and publish data:

Chemistry Letters p. 1795 - 1798 (1984)

Update date:2022-07-29

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Authors:

Fujisawa, Tamotsu

Umezu, Kazuto

Kawashima, Masatoshi

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Article abstract of DOI:10.1246/cl.1984.1795

(Z)-4-Hexenolide reacted regioselectively with diorganocuprates to give (Z)-4-alkenoic acids in high yields.Synthetic utility was demonstrated by the convenient synthesis of cis-jasmone.

Full text of DOI:10.1246/cl.1984.1795

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