Tetrahedron p. 4013 - 4018 (1984)
Update date:2022-08-05
Topics:
Mori, Ichiro
Takai, Kazuhiko
Oshima, Koichiro
Nozaki, Hitosi
Such organoaluminium reagents as iBu3Al, PhC<*>CAlEt2, and Et2AlSPh mediate the title reactions in three different directions. (1) <3,3> sigmatropic rearrangement producing 7-membered rings. (2) isomerization to form vinylcyclopropane derivatives and (3) SN2' type reaction with phenylthio anion via oxolane ring opening.
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