REPLACEMENT OF A CARBONYL GROUP OF CYCLIC KETONES BY A SULFUR OR A NITROGEN ATOM. A NEW METHOD FOR TRANSFORMATION OF STEROIDAL KETONES INTO THIA- OR AZASTEROIDS

DOI: 10.1246/cl.1984.2079

Source and publish data:

Chemistry Letters p. 2079 - 2082 (1984)

Update date:2022-08-04

Topics:

Authors:

Suginome, Hiroshi

Yamada, Shinji

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Article abstract of DOI:10.1246/cl.1984.2079

We describe a new and versatile method for transforming cyclic ketones into cyclic sulfides or cyclic amines with the same ring size via five-step procedure.The transformation is stereospecific with regard to the chiral center adjacent to the carbonyl gro

Full text of DOI:10.1246/cl.1984.2079

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