A NOVEL TYPE SECOIRIDOID GLUCOSIDE, HYDRANGENOSIDE A FROM HYDRANGEA MACROPHYLLA

DOI: 10.1016/S0040-4039(00)78838-1

Source and publish data:

Tetrahedron Letters p. 1059 - 1062 (1980)

Update date:2022-07-29

Topics: Stereochemistry Lactones Bromide Catalytic reduction Pd-C Acetylation Iridoid Benzene ring Demesylation Olefin Geometrical isomers Catalytic hydrogenation Benzyloxy

Authors:

Inouye, Hiroyuki

Takeda, Yoshio

Uesato, Shinichi

Uobe, Kenichi

Hashimoto, Toshiro

Shingu, Tetsuro

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Article abstract of DOI:10.1016/S0040-4039(00)78838-1

Hydrangenoside A, isolated along with its three congeners from Hydrangea macrophylla, was proved to have a novel type of structure which is thought to be biosynthesized through an aldol-type condensation of secologanin with a unit formed by the shikimate-

Full text of DOI:10.1016/S0040-4039(00)78838-1

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