Archiv der Pharmazie p. 261 - 270 (1985)
Update date:2022-08-03
Topics:
Brieskorn, Carl Heinz
Ryu, Chung-Kyu
The hydroxymethyl derivatives of isopinocamphone, isocaranone, carvomenthone and menthone were prepared using formaldehyde and alkaline catalysis.The preferential position of attack is the more highly branched carbon atom of the enolate.The addition of formaldehyde proceeds regio- and stereoselectively with the bicyclic monoterpenones and regioselectively only with the monocyclic monoterpenones.
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Doi:10.1021/ja00297a078
(1985)Doi:10.1135/cccc19842932
(1984)Doi:10.1021/ja01167a605
(1950)Doi:10.1039/P19870001713
(1987)Doi:10.1016/0040-4020(96)00083-X
(1996)Doi:10.1016/j.tetlet.2016.12.007
(2017)
