Novel Porphyrins from Copper(II)-Mediated Cyclizations of 1',8'-Dimethyl-a,c-biladiene Salts: Mechanism of the Cyclization Reaction

DOI: 10.1021/jo00212a014

Source and publish data:

Journal of Organic Chemistry p. 2073 - 2080 (1985)

Update date:2022-07-29

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Authors:

Smith, Kevin M.

Minnetian, Ohannes M.

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Article abstract of DOI:10.1021/jo00212a014

Copper(II)-mediated cyclizations of the 1',8'-dimethyl-a,c-biladiene 8 under various conditions afford the expected porphyrin 7, along with γ-methyl- (9), γ-(dialkylamino)- (10 and 11), 6-formyl- (12), and γ-formylporphyrins (13).Carbon-13-enriched a,c-bi

Full text of DOI:10.1021/jo00212a014

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