Journal of Organic Chemistry p. 2527 - 2533 (1985)
Update date:2022-07-30
Topics:
Shono, Tatsuya
Kise, Naoki
Masuda, Mitsuharu
Suzumoto, Takeshi
Cathodic reduction of a system comprising carbon tetrachloride, chloroform, and an aldehyde led to an effective anionic chain reaction.The best current efficiency observed was about 1*104 percent .Such a chain reaction is an effective synthetic method for 1,1,1-trichloro-2-alkanols.The reaction system consisting of methyl trichloroacetate, methyl dichloroacetate, and an aldehyde and several other systems also exhibited a similar pattern of chain reaction.
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