Journal of Organic Chemistry p. 2474 - 2480 (1985)
Update date:2022-08-05
Topics: Regioselectivity Yield Deprotonation Rearrangement Chromatography Nucleophilic addition Cyclization Substitution Steric Effects Electronic effects Solvent Effects Reaction Optimization Spectroscopic Analysis Tautomerization Heterocyclic compound Mechanistic study
Agasimundin, Yankanagouda S.
Oakes, Fred T.
Leonard, Nelson J.
Annelation of isocytosine and 6-substituted isocytosines with methyl N-cyanomethanimidate and sodium methoxide in methanol leads to pyrimidotriazines.The structures of the products reveal substituent influence on the direction of cyclization and rearrange
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