Tetrahedron p. 5167 - 5170 (1984)
Update date:2022-08-05
Topics:
Ende, M.
Luftmann, H.
Aldehydes react with MSTFA (N-methyl-N-trimethylsilyl-trifluoroacetamide) to give E/Z-silylenolethers and surprisingly addition products of the reagent to the carbonyl group.The mass spectra of the MSTFA/aliphatic aldehyde adducts are dominated by a key fragment of m/z 228 formed by elimination of the alkyl part.With MSTFA/aromatic aldehyde adducts this fragmentation is replaced by M-H and M-CH3N.8COCF3 (M-126 amu) ions.
View MoreAnhui Sholon New Material Technology Co., Ltd.
website:http://www.sholonchem.com
Contact:+86-550-5261666
Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province
Qingdao XinYongAn Chemicals Co., Ltd
Contact:+86-532-81107967
Address:Chengyang dual-port industrial park by the sea，Qingdao
Contact:+86-21-61318535
Address:Building 29,No.2139 Xizha Road, Fengxian District, Shanghai
Tai zhou world Pharm & Chem Co., Ltd
Contact:+86-576-85301198
Address:Rome 1001,wangjiang plaza,unti 2,jinshan east Road linhai,zhejiang,china
Hubei Lansun Biochemical Pharmaceutical Co., Ltd
Contact:714-6395977
Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China
Doi:10.1039/c0cc04370b
(2011)Doi:10.1016/j.jorganchem.2011.02.004
(2011)Doi:10.1016/j.tetlet.2010.11.001
(2011)Doi:10.1021/jm00165a022
(1990)Doi:10.1021/jo2005445
(2011)Doi:10.1016/j.jep.2010.07.009
(2010)
