Catalytic "Homo-Reformatsky" Reaction. Ambident Chemical Reactivities of the Zinc Homoenolate of Propionate

DOI: 10.1021/jo00215a050

Source and publish data:

Journal of Organic Chemistry p. 2802 - 2804 (1985)

Update date:2022-08-05

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Authors:

Oshino, Hiroji

Nakamura, Eiichi

Kuwajima, Isao

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Article abstract of DOI:10.1021/jo00215a050

Zinc halide catalyzed reaction of 1-alkoxy-1-siloxycyclopropane with carbonyl compounds gives 4-siloxy esters, while a related reaction with acid chlorides produces either 4-keto esters or (acyloxy)cyclopropanes.

Full text of DOI:10.1021/jo00215a050

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