SYNTHESIS OF α-PHOSPHORYLATED CYCLOPENTANONES BY INTRAMOLECULAR CARBENOID CYCLIZATIONS OF α-DIAZO β-KETO ALKYLPHOSPHONATES AND PHOSPHINE OXIDES

DOI: 10.1016/S0040-4039(00)96925-9

Source and publish data:

Tetrahedron Letters p. 6605 - 6608 (1987)

Update date:2022-08-05

Topics:

Authors:

Corbel, Bernard

Hernot, Dominique

Haelters, Jean-Pierre

Sturtz, Georges

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)96925-9

α-diazo β-ketoalkylphosphonates and phosphine oxides undergo intramolecular carbenoid cyclizations under rhodium (II) catalysis to afford substituted diethoxyphosphono-2 and diphenylphosphono-2 cyclopentanones which, under Wittig-Horner conditions, lead t

Full text of DOI:10.1016/S0040-4039(00)96925-9

Products guided by the article

Product name:diethyl<(3-methyl)-oxocyclopent-2-yl>phosphonate

Cas No:96816-53-4

R&D Labs maybe for 96816-53-4

GN chemicals co.,ltd

Contact:86 311 85902108 / 85902109

Address:room 1001-1005 ,huanghe Road ,shijiazhuang ,China
AllyChem Co., Ltd., Dalian, China（BBChem）

Contact:+86-411-62313318/62313328

Address:No.5 of Jinbin Road, Jinzhou New District, Dalian City, Liaoning Province, P.R.China
Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Antimex Chemical Limied

website:http://www.antimex.com

Contact:0086-21-50563169

Address:Room1027,No.Jinyu Road,Pudong
Nanjing Zelang Medical Technology Co. Ltd

Contact:86-25-83063290/13770714480

Address:Ganjiabian 108# 01 Unit,701-702 room,Yao Hua Street,Qixia District,Nanjing,Jiangsu,China

Relevant to this article

Synthesis of Methanethial S-Oxide (Sulfine) and Alkanethial S,S-Dioxides by Fluorodesilylation. Stereochemistry of Their Cyclopentadiene Diels-Alder Adducts

Doi:10.1016/S0040-4039(00)99062-2
(1985)
Fluoroprostaglandins: Totl Synthesis of (+)-13-Fluoroprostaglandin F_2α Methyl Ester

Doi:10.1021/jo00217a019
(1985)
Fast and green microwave-Assisted conversion of essential oil allylbenzenes into the corresponding aldehydes via alkene isomerization and subsequent potassium permanganate promoted oxidative alkene group cleavage

Doi:10.3390/molecules14093411
(2009)
Amino acids and peptides, XLVIII. Total synthesis and biomimetic formation of clionamide derivatives

Doi:10.1002/jlac.198519850414
(1985)
CUAUTHEMONE SESQUITERPENOIDS FROM BLUMEA ALATA

Doi:10.1016/S0031-9422(00)80757-8
(1985)
PAVONININS, SHARK-REPELLING AND ICHTHYOTOXIC STEROID N-ACETYLGLUCOSAMINIDES FROM THE DEFENSE SECRETION OF THE SOLE PARDACHIRUS PAVONINUS (SOLEIDAE)

Doi:10.1016/S0040-4020(01)96470-1
(1985)

Article Doi