Unprecedented outcome of base-promoted neber rearrangement of O-Mesyloxime of 2-aryl-1,2,3,4-tetrahydro-1-methylsul fonyl-4-quinolone-synthesis of 4-amino-2-arylquinolines

Article abstract of DOI:10.1080/10426500008076551

O-Mesyloximes derived from 2-aryl-1,2,3,4-tetrahydro-1-methylsulfonyl-4-quinolones react with sodium ethoxide in ethanol to afford the 4-amino-2-arylquinolines in high yield. No traces of the 3-amino-2-aryl-4-quinolones expected from the Neber rearrangeme

Full text of DOI:10.1080/10426500008076551

This article was downloaded by: [Moskow State Univ Bibliote]
On: 29 November 2013, At: 04:27
Publisher: Taylor & Francis
Informa Ltd Registered in England and Wales Registered Number:
1072954 Registered office: Mortimer House, 37-41 Mortimer Street,
London W1T 3JH, UK
Phosphorus, Sulfur, and
Silicon and the Related
Elements
Publication details, including instructions for
authors and subscription information:
http://www.tandfonline.com/loi/gpss20
UNPRECEDENTED OUTCOME
OF BASE-PROMOTED
NEBER REARRANGEMENT
OF O-MESYLOXIME
OF 2-ARYL-1,2,3,4-
TETRAHYDRO-1-METHYLSUL
FONYL-4-QUINOLONE-
SYNTHESIS OF 4-AMINO-2-
ARYLQUINOLINES
Malose J. Mphahlele a , Omankutty
Gheevarghese a & Nkosinathi F. H. Makhubela a
a Department of Chemistry and Biochemistry ,
Medical University of Southern Africa , P.O. Box
235, MEDUNSA, 0204, South Africa
Published online: 19 Dec 2006.
To cite this article: Malose J. Mphahlele , Omankutty Gheevarghese & Nkosinathi
F. H. Makhubela (2000) UNPRECEDENTED OUTCOME OF BASE-PROMOTED NEBER
REARRANGEMENT OF O-MESYLOXIME OF 2-ARYL-1,2,3,4-TETRAHYDRO-1-
METHYLSUL FONYL-4-QUINOLONE- SYNTHESIS OF 4-AMINO-2-ARYLQUINOLINES,
Phosphorus, Sulfur, and Silicon and the Related Elements, 166:1, 303-314, DOI:
10.1080/10426500008076551
To link to this article: http://dx.doi.org/10.1080/10426500008076551

PLEASE SCROLL DOWN FOR ARTICLE
Taylor & Francis makes every effort to ensure the accuracy of all
the information (the “Content”) contained in the publications on our
platform. However, Taylor & Francis, our agents, and our licensors
make no representations or warranties whatsoever as to the accuracy,
completeness, or suitability for any purpose of the Content. Any opinions
and views expressed in this publication are the opinions and views of
the authors, and are not the views of or endorsed by Taylor & Francis.
The accuracy of the Content should not be relied upon and should be
independently verified with primary sources of information. Taylor and
Francis shall not be liable for any losses, actions, claims, proceedings,
demands, costs, expenses, damages, and other liabilities whatsoever
or howsoever caused arising directly or indirectly in connection with, in
relation to or arising out of the use of the Content.
This article may be used for research, teaching, and private study
purposes. Any substantial or systematic reproduction, redistribution,
reselling, loan, sub-licensing, systematic supply, or distribution in any
form to anyone is expressly forbidden. Terms & Conditions of access
and use can be found at http://www.tandfonline.com/page/terms-and-
conditions