Mechanism of Amine and Amide Ion Substitution Reactions at the Carbon-Nitrogen Double Bond.

DOI: 10.1021/jo00218a021

Source and publish data:

Journal of Organic Chemistry p. 3348 - 3355 (1985)

Update date:2022-08-03

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Authors:

Johnson, James Elver

Ghafouripour, Abdolkarim

Arfan, Mohammad

Todd, Susan L.

Sitz, Deborah A.

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Article abstract of DOI:10.1021/jo00218a021

Reactions of the (Z)-hydroximoyl chlorides 3a-e with secondary amines without solvent at 32 deg C for 24 h give high yields of (Z)-benzamidoximes 7a-f.Although the amidoximes 7a-f do not isomerize under the reaction conditions, they isomerize to the E iso

Full text of DOI:10.1021/jo00218a021

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