Gold catalysis: Evidence for the in-situ reduction of gold(III) during the cyclization of allenyl carbinols

DOI: 10.1002/ejoc.200600009

Source and publish data:

European Journal of Organic Chemistry p. 1387 - 1389 (2006)

Update date:2022-08-04

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Authors:

Hashmi, A. Stephen K.

Blanco, M. Carmen

Fischer, Dirk

Bats, Jan W.

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Article abstract of DOI:10.1002/ejoc.200600009

Products of an oxidative coupling were obtained in the gold(III)-catalyzed cycloisomerization of tertiary allenyl carbinols. The absence of reduced organic products and an increase of these coupling products with the amount of gold(III) catalyst suggests

Full text of DOI:10.1002/ejoc.200600009

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