Preparation of the Isocyanide Complexes trans- (R = Me or But) and their Reactions with Acid to give Carbyne Complexes. X-Ray Crystal Structure of trans-

DOI: 10.1039/DT9810001629

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1629 - 1634 (1981)

Update date:2022-07-30

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Authors:

Pombeiro, Armando J. L.

Carvalho, Maria Fernanda N. N.

Hitchcock, Peter B.

Richards, Raymond L.

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Article abstract of DOI:10.1039/DT9810001629

The complexes trans- (1, R = Me or Bu^t) have been prepared by replacement of dinitrogen in trans-.The alkyl isocyanide ligands in complexes (1) undergo electrophilic attack at the nitrogen atom by mineral acid

Full text of DOI:10.1039/DT9810001629

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