Stereochemistry of the Reductive Alkylation of α,β-Epoxy Ketones

DOI: 10.1021/jo00219a011

Source and publish data:

Journal of Organic Chemistry p. 3473 - 3481 (1985)

Update date:2022-08-05

Topics:

Authors:

McChesney, James D.

Thompson, Thomas N.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00219a011

α-Epoxy ketones have been found to be useful intermediates for regiospecific alkylation of ketones.We have examined the steric course of the alkylation and shown it to be highly stereoselective.

Full text of DOI:10.1021/jo00219a011

Products guided by the article

Product name:C₁₁H₁₅⁽²⁾H₃O₂

Cas No:97570-28-0

R&D Labs maybe for 97570-28-0

Water Chemical Co.,LTD

Contact:+86-21-6856-1349 523-87676172

Address:No16 . BinJiang Road . Taixing Economy Developing Area .JiangSu Province . China
Hebei Tianxiang Biological & Pharmaceutical Co., Ltd

Contact:86-0312-6615158

Address:No 42 fazhan street qingyuan county
Xi'an North Information Industry Co., Ltd. Weilv Chemical Department

Contact:+86-29-88156413

Address:Jixiang Road 99 Xi'an Shaanxi Province
Henan zhongda Biological Engineering Co., Ltd

Contact:86-28-18109029985

Address:shenzhou road,xuedian industrial estate,zhengzhou city,henan province CHN
Nanjing Fubang Chemical Co.,Ltd

Contact:+86-25-83179199

Address:5F,Tianzheng international plaza,No399 Zhongyang Road ,Nanjing China

Relevant to this article

THERMAL REARRANGEMENTS OF CYCLIC ALLENES via RETRO-ENE REACTIONS

Doi:10.1016/S0040-4039(00)98820-8
(1985)
Sulfur dioxide prodrugs: Triggered release of SO₂ via a click reaction

Doi:10.1039/c6cc08844a
(2017)
Limatulone, a Potent Defensive Metabolite of the Intertidal Limpet Collisella limatula

Doi:10.1021/jo00218a044
(1985)
Positional and cis-trans N-methylaminotriphosphonitriles. The use of H¹ nuclear magnetic resonance in configurational analysis

Doi:10.1021/ic50028a027
(1965)
Low Temperature Free-Radical Reactions Initiated with tert-Butyl p-Benzoylperbenzoate. Selective Acyl Radical Additions to Substituted Olefins

Doi:10.1021/jo00219a015
(1985)
Search for Singlet Oxygen in the Decomposition of Hydrogen Peroxide by Mineral Compounds in Aqueous Solutions

Doi:10.1021/ja00307a002
(1985)

Article Doi