Journal of Organic Chemistry p. 5155 - 5160 (1980)
Update date:2022-08-03
Topics:
Harpp, David N.
Ash, David K.
Smith, Roger A.
Tris(dialkylamino)phosphines effect a rapid desulfurization of trisulfides to disulfides under mild conditions.The reaction mechanism involves a bimolecular process, proceeding by the rate-determining formation of a phosphonium salt intermediate.The central sulfur atom of a diaryl trisulfide is removed in the process, while a dialkyl trisulfide loses a terminal sulfur atom to the aminophosphine.
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