PREPARATION AND REACTIONS OF SOME STERICALLY HINDERED SILANOLS, INCLUDING SILANETRIOL

DOI: 10.1016/0022-328X(85)87289-2

Source and publish data:

Journal of Organometallic Chemistry p. 267 - 276 (1985)

Update date:2022-07-29

Topics: Reactions Sterically hindered Preparation

Authors:

Damja, Ramadan I.

Eaborn, Colin

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Article abstract of DOI:10.1016/0022-328X(85)87289-2

The silanol TsiSiMe2OH (Tsi = (Me3Si)3C) has been made by hydrolysis of the iodide TsiSiMe2I in H2O/dioxane or H2O/Me2SO.It has been shown to react with some acid chlorides RCOCl (R = Me, Et, ClCH2, Ph, 4-O2NC6H4, and 3,5-(O2N)2C6H3) and anhydrides (RCO)2

Full text of DOI:10.1016/0022-328X(85)87289-2

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