Journal of the Chemical Society. Chemical communications p. 237 - 238 (1985)
Update date:2022-08-04
Topics: Formation Experimental Chemical terms
Bonini, Bianca F.
Maccagnani, Gaetano
Mazzanti, Germana
Zwanenburg, Binne
Diarylthioketone S-oxides react with the 2H-azirine (1) in the presence of boron trifluoride-diethyl ether to give the oxathiazines (3) via a 1,3-cyclization across the sulphine C-S-O bond; the oxathiazines (3) rearrange thermally to the sulphoxides (5).
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