On-Off-switched Crown Ether-Metal Ion Complexation by Photoinduced Intramolecular Ammonium Group 'Tail-biting'

DOI: 10.1039/c39840000727

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 727 - 729 (1984)

Update date:2022-08-02

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Authors:

Shinkai, Seiji

Ishihara, Midori

Ueda, Kaori

Manabe, Osamu

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Article abstract of DOI:10.1039/c39840000727

A new photoresponsive crown ether with an ammonium-group tail was synthesised in which the ion-binding ability changes in response to photoirradiation because of competitive intramolecular 'tail-biting' in the cis-form produced by photoisomerisation.

Full text of DOI:10.1039/c39840000727

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