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Synthesis of hetero-binuclear derivatives of the tetrathiolato complexes [Mo(η-C5H5CH2SR)2)], R = Prn and Ph, with platinum, palladium, and rhodium

DOI: 10.1016/0022-328X(85)87172-2

Source and publish data:

Journal of Organometallic Chemistry p. 225 - 231 (1985)

Update date:2022-09-26

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Authors:

O'hare, DermotO'hare, Dermot

Green, Malcolm L.H.Green, Malcolm L.H.

Cloke, F.Geoffrey N.Cloke, F.Geoffrey N.

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Article abstract of DOI:10.1016/0022-328X(85)87172-2

The compound Mo(η-C5H4(CH2)2SPrn)2(SPrn)2 acts as a bidentate ligand giving the heteronuclear bi-metallic compounds [Mo(η-C5H4CH2CH2SPrn)2-(SPrn)2(PtCl2)],[Mo(η-C5H4CH2CH2SPrn)2(SPrn)2(PdCl2)2], [Mo(η-C5C4CH2CH2SPrn)2(SPrn)2(RhCl3)2], [Mo(η-C5H4CH2CH2SPrn)2(μ-SPrn)2Rh(dppe)]BF4, [Mo(η-C5H4CH2CH2SPrn)2(μ-SPrn)2(COD)Rh]Cl, [Mo(η-C5H4CH2CH2SPrn)2-(μ-SPrn)2Pt(PPh3)2](PF6)2, and the compound [Mo(η-C5H4(CH2)2-μ-SPh)2Cl2Rh(COD)]Cl bonds via the ring-sulphur substituents giving [Mo(η-C5H4(CH2)2-μ-SPh)2-Cl2Rh(COD)]Cl.

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Full text of DOI:10.1016/0022-328X(85)87172-2

Products guided by the article

Product name:[μ2-(SR)2bis[η-(3-phenyl-3-thiapropyl)cyclopentadienyl]dichloromolybdenum](cycloocta-1,4-diene)rhodium hexafluorophosphate

Cas No:98183-65-4

98183-65-4

R&D Labs maybe for 98183-65-4

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