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Studies in the Regioselectivity of the Vinylogous Reformatsky Reaction with Ambident Electrophiles: Reversibility, Mechanism, and Synthetic Utility

DOI: 10.1021/jo00222a020

Source and publish data:

Journal of Organic Chemistry p. 4300 - 4306 (1985)

Update date:2022-08-04

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Authors:

Hudlicky, TomasHudlicky, Tomas

Natchus, Michael G.Natchus, Michael G.

Kwart, Lawrence D.Kwart, Lawrence D.

Colwell, Barry L.Colwell, Barry L.

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Article abstract of DOI:10.1021/jo00222a020

The additions of the organozinc reagent derived from ethyl 4-bromocrotonate to several unsaturated carbonyl substrates were investigated.The regiochemical outcome is reported for each reaction and some suggestions are advanced regarding the mechanism and

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Full text of DOI:10.1021/jo00222a020

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