Some water-soluble Schiff-base complexes of nickel(II): The role of water

DOI: 10.1039/DT9850001451

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1451 - 1454 (1985)

Update date:2022-08-03

Topics:

Authors:

Evans, Dennis F.

Missen, Paul H.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9850001451

Disodium nickelate(II), Na2, and disodium bisnickelate(II) have been prepared.Electronic spectra and magnetic susceptibility measurements show that in aqueous solution there is an equilibrium between the square-planar forms and six-co-ordinate species produced by co-ordination of two water molecules.Thermodinamic parameters are reported for the Na2 system.The room-temperature i.r. spectrum of solid (diamagnetic) Na2*2H2O gives two well resolved bands in the O-H stretching region.One of these is extremely sharp (bandwidth 16 cm^-1) and occurs at an unusually high frequency (3630 cm^-1).The i.r. spectra of samples having various extents of deuteriation show that the two water molecules are crystallographically equivalent, with C₁ site symmetry.In each H2O, one hydrogen atom is almost non-hydrogen-bonded while the other is involved in a hydrogen bond of moderate strength.

Full text of DOI:10.1039/DT9850001451

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₁₇H₁₆N₂O₈S₂^(2-)*2Na⁽¹⁺⁾

Cas No:98603-68-0

R&D Labs maybe for 98603-68-0

LINAN HAIHUA CHEMICAL CO LTD

Contact:86-571-61063068

Address:LINAN
Beijing Mesochem Technology Co.,LTD

website:http://www.mesochem.com

Contact:0086-10-57862036

Address:2301, Floor 23, Building 9 Lippo Plaza, Yard 8 Ronghua Middle Road, ETDZ, Beijing, China
Henan Sinotech Import&Export Corporation

website:http://www.hasinotech.com

Contact:86-371-86181678

Address:No. 260, Dongming Road,Jinshui District
QINGDAO ON-BILLION INDUSTRAIL CO.,LTD

website:http://www.obn.com.cn

Contact:+86-15005320811 +86-532-80681989

Address:F35 Parkson Mansion No.44-60 Zhongshan Rd.
He Bei Shun Er Chemical Co., LTD.

Contact:86-0311-86996932/86860168

Address:No 18,North street

Relevant to this article

Studies in biomimetic alkaloid syntheses. 13. Total syntheses of racemic aspidofractine, pleiocarpine, pleiocarpinine, kopsinine, N-methylkopsanone, and kopsanone

Doi:10.1021/jo00224a027
(1985)
Light-induced Intramolecular Electron Transfer from a Porphyrin linked to a p-Benzoquinone by a Rigid Spacer Group

Doi:10.1039/c39850000559
(1985)
A Novel Synthesis of Indole Ring System

Doi:10.1039/c39850000618
(1985)
7-Deaza-2'-deoxyinosine: A stable nucleoside with the ambiguous base pairing properties of 2'-deoxyinosine

Doi:10.1080/15257779908043087
(1999)
Aminohydroxy phosphine oxide ligands in ruthenium-catalysed asymmetric transfer hydrogenation reactions

Doi:10.1016/j.tetasy.2004.04.040
(2004)
Biomimetic Models for Cysteine Proteases. 3. Acylation of Imidazolium-Thiolate Zwitterions by p-Nitrophenylacetate as a Model for the Acylation Step and Demonstration of Intramolecular General-Base-Catalyzed Delivery of H2O by Imidazole to Thiol Esters as a Model for the Deacylation Step

Doi:10.1021/ja00311a074
(1985)

Article Doi