Formation and Crystal Structure of NMe2NHCH2CHPPh2CH2CH2PPh2>Cl containing a Novel Tridentate Ylide Ligand formed by Intramolecular Phosphinovinylation

DOI: 10.1039/c39870000643

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 643 - 644 (1987)

Update date:2022-08-05

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Authors:

Herring, Andrew M.

Markham, David P.

Shaw, Bernard L.

Thornton-Pett, Mark

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Article abstract of DOI:10.1039/c39870000643

Treatment of cis- with Me2NNH2 gives the title compound, formed by successive conjugate addition to the vinyl groups, including attack by one P-atom on a vinyl group of an adjacent co-ordinated PPh2CH=CH2 ligand; some reactions of the

Full text of DOI:10.1039/c39870000643

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