PREPARATION OF PYRANOID GLYCAL DERIVATIVES FROM PHENYL THIOGLYCOSIDES AND GLYCOSYL PHENYL SULPHONES

DOI: 10.1016/0008-6215(89)84061-3

Source and publish data:

Carbohydrate Research p. 81 - 96 (1989)

Update date:2022-07-30

Topics: Preparation Experimental

Authors:

Fernandez-Mayoralas, Alfonso

Marra, Alberto

Trumtel, Michel

Veyrieres, Alain

Sinay, Pierre

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Article abstract of DOI:10.1016/0008-6215(89)84061-3

Phenyl thioglycopyranosides with various protecting groups (acetal, ether, ester) underwent reductive lithiation at C-1, followed by rapid elimination of the 2-substituent, when treated with lithium naphthalenide in tetrahydrofuran at low temperature.Thus

Full text of DOI:10.1016/0008-6215(89)84061-3

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