Journal of the Chemical Society. Perkin transactions I p. 747 - 752 (1987)
Update date:2022-08-04
Topics:
von Rosenberg, Joseph L.
Pinder, A. Reginald
The Friedel-Crafts acetylation of several (arene)tricarbonylchromium complexes have been investigated.From the results it is concluded that the tricarbonylchromium group deactivates to a small extent towards electrophilic substitution the ring to which it is attached.In the case of tricarbonyl(diphenylmethane)chromium (1; n=1), however, attack occurred on both rings to about an equal extent, possible explanations for this unexpected behaviour are advanced.
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