Stereospecific Generation of α- and β-Glycosyl-lithium Reagents from Glycosyl-stannanes: a Stereocontrolled Route to α- and β-C-Glycosides

DOI: 10.1039/c39850000894

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 894 - 895 (1985)

Update date:2022-08-02

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Authors:

Lesimple, Patrick

Beau, Jean-Marie

Sinay, Pierre

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Article abstract of DOI:10.1039/c39850000894

Treatment of α- and β-D-tri-n-butylstannyl-glucopyranosides with n-butyl-lithium at -78 deg C generates configurationally stable α- and β-D-glycosyl-lithium species which accept electrophiles with retention of configuration.

Full text of DOI:10.1039/c39850000894

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