Stereospecific Generation of α- and β-Glycosyl-lithium Reagents from Glycosyl-stannanes: a Stereocontrolled Route to α- and β-C-Glycosides

DOI: 10.1039/c39850000894

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 894 - 895 (1985)

Update date:2022-08-02

Topics:

Authors:

Lesimple, Patrick

Beau, Jean-Marie

Sinay, Pierre

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39850000894

Treatment of α- and β-D-tri-n-butylstannyl-glucopyranosides with n-butyl-lithium at -78 deg C generates configurationally stable α- and β-D-glycosyl-lithium species which accept electrophiles with retention of configuration.

Full text of DOI:10.1039/c39850000894

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:phenyl-(3,4,6-tri-O-benzyl-2-deoxy-β-D-arabino-hexapyranosyl)ketone

Cas No:98933-78-9

R&D Labs maybe for 98933-78-9

shanghai jiuling chemical co.,ltd.

Contact:+86-21-50387295

Address:Zaozhuang Road, Pudong, Shanghai City. China
Jiaxing Taixin Pharmaceutical Chemical Co., Ltd

Contact:0573-82613601

Address:Chemical Park, Jiaxing, Zhejiang, China
Shouguang Nuomeng Chemical Co., Ltd.

Contact:+86-536-5119508/18363669993

Address:Hou Zhen Industrial Park, Shouguang, Shandong, China
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
Shanghai chemrole co.,ltd

Contact:021-50278900

Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china

Relevant to this article

The Complete Characterization of a Rhodium Lewis Acid-Dipolarophile Complex as an Intermediate for the Enantioselective Catalytic 1,3-Dipolar Cycloaddition of C,N-Diphenylnitrone to Methacrolein

Doi:10.1021/ja031995z
(2004)
Chiral DBFOX/Ph Complex catalyzed enantioselective nitrone cycloadditions to α,β-unsaturated aldehydes

Doi:10.1021/ol0361148
(2004)
A general chemoenzymatic synthesis of enenatiopures cis β-amino alcohols from microbially derived cis-glycols

Doi:10.1055/s-1998-6082
(1998)
Doi:10.1002/hlca.19780610511
(1978)
Asymmetric synthesis of spiro 2-pyrrolidin-5-ones, 2-piperidin-6-ones and 1-isoindolin-3-ones. Part 1: N-acyliminium ion cyclisations with an internal arene nucleophile

Doi:10.1016/j.tet.2003.10.128
(2004)
Synthesis of aromatic carboxylic acids by carbonylation of aryl halides in the presence of epoxide-modified cobalt carbonyls as catalysts

Doi:10.1007/s11167-005-0619-y
(2005)

Article Doi