Inorganica Chimica Acta p. 279 - 285 (1988)
Update date:2022-08-05
Topics:
Franzoni, Doriano
Pelizzi, Giancarlo
Predieri, Giovanni
Tarasconi, Pieralberto
Pelizzi, Corrado
Three new silver - tin complex salts with cis-1,2-bis(diphenylphosphino)ethylene have been synthesized. IR, 31P and 119Sn NMR and conductivity data are reported and discussed together with the X-ray crystal structure of one of them, [Ag(cdppet)2][SnPh3(NO)3)2]. The silver atom is distorted tetrahedrally surrounded by the four phosphorus atoms of the two cdppet ligands. The tin atom is in a slightly distorted trigonal bipyramidal geometry with the phenyl carbon atoms in the equatorial plane and two oxygen atoms from monodentate nitrate groups at the apices.
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