
Journal of Organic Chemistry p. 5487 - 5490 (1985)
Update date:2022-08-05
Topics:
Nishizawa, Mugio
Nademoto, Yayoi
Sastrapradja, Setijati
Shiro, Motoo
Hayashi, Yuji
Characteristic bitter principles, named dukunolides A, B, and C, in seeds of Lansium domesticum have been proven to be skeletally new tetranortriterpenoids 1, 2, and 3.The structure of 1 is definitely established by X-ray analysis, and that of 2 is confirmed by the chemical correlation with 1 by epoxidation.The absolute configuration of these compounds has been deduced from that of dukunolide C p-bromobenzonate, established by X-ray study.
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(1986)