Di-?-methane Rearrangement of Highly Sterically Congested Molecules: Inhibition of Free-Rotor Energy Dissipation. Mechanistic and Exploratory Organic Photochemistry

DOI: 10.1021/jo00352a013

Source and publish data:

Journal of Organic Chemistry p. 196 - 207 (1986)

Update date:2022-08-04

Topics:

Authors:

Zimmerman, Howard E.

Schissel, David N.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00352a013

Four highly sterically congested di-?-methane reactants were synthesized and their photochemistry was studied.These were 1,1,5,5-tetraphenyl-3,3-diisopropyl-1,4-pentadiene (1), 1,1,5,5-tetraphenyl-3-isopropyl-3-methyl-1,4-pentadiene(2), 1,1-dimesityl-5,5-

Full text of DOI:10.1021/jo00352a013

Products guided by the article

Product name:1,1-diphenyl-2,2-dimethyl-3-(2,2-dimesitylvinyl)cyclopropane

Cas No:99343-01-8

R&D Labs maybe for 99343-01-8

JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Chongqing Yawei Fine Chemical Co.,Ltd

Contact:0086-23-62849407

Address:Ziyou village, Nanquan town, Banan district, Chongqing China
Daqing E-shine Chemical Co.,LTD

Contact:0086-024-31285112

Address:Hongweiyuan area, Ranghulu district
Hubei Lingsheng Pharmaceuticals Co., Ltd.

Contact:+86-0710-3538058

Address:Xiangyang City Xiangcheng Economic Development Zone, Hubei Province
Xiamen XM-Innovation Chemical Co., Ltd

Contact:+86-592-3216205

Address:Unit Q, 11/F, No.1 Office Building, Wuyuan Bay Business Center, Huli District, Xiamen City, Fujian Province, P.R.C

Relevant to this article

The Reactions of α-Arylsulfonoxy Ketones with Nucleophiles

Doi:10.1021/jo00352a002
(1986)
Fungal Dioxygenase AsqJ Is Promiscuous and Bimodal: Substrate-Directed Formation of Quinolones versus Quinazolinones

Doi:10.1002/anie.202017086
(2021)
Synthesis of the Carbohydrate Moiety of Bleomycin. 1,3,4,6-Tetra-O-substituted L-Gulose Derivatives

Doi:10.1021/jo00350a073
(1985)
Doi:10.1016/S0040-4039(00)70886-0
(1962)
A CONVENIENT PROCEDURE FOR THE PREPARATION OF DINUCLEOSIDE PHOSPHATES BY THE USE OF A BIFUNCTIONAL PHOSPHORYLATING REAGENTS, 2-CHLOROPHENYLPHOSPHOROBIS(NITROBENZOTRIAZOLIDE)

Doi:10.1246/cl.1985.949
(1985)
Doi:10.1021/jo01144a011
(1951)

Article Doi