Di-?-methane Rearrangement of Highly Sterically Congested Molecules: Inhibition of Free-Rotor Energy Dissipation. Mechanistic and Exploratory Organic Photochemistry

DOI: 10.1021/jo00352a013

Source and publish data:

Journal of Organic Chemistry p. 196 - 207 (1986)

Update date:2022-08-04

Topics:

Authors:

Zimmerman, Howard E.

Schissel, David N.

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Article abstract of DOI:10.1021/jo00352a013

Four highly sterically congested di-?-methane reactants were synthesized and their photochemistry was studied.These were 1,1,5,5-tetraphenyl-3,3-diisopropyl-1,4-pentadiene (1), 1,1,5,5-tetraphenyl-3-isopropyl-3-methyl-1,4-pentadiene(2), 1,1-dimesityl-5,5-

Full text of DOI:10.1021/jo00352a013

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