General Acid Catalysis in the Hydrolysis of 1,3-Dioxolanes and 1,3-Oxathiolanes. The Hydrolysis of Acetals and Thioacetals of p-(Dimethylamino)benzaldehyde

DOI: 10.1021/ja00269a048

Source and publish data:

Journal of the American Chemical Society p. 2425 - 2430 (1986)

Update date:2022-08-03

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Authors:

Fife, Thomas H.

Natarajan, R.

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Article abstract of DOI:10.1021/ja00269a048

Rate constants have been determined for hydrolysis of acetal and O,S-thioacetal derivatives of p-(dimethylamino)benzaldehyde in H2O.The plots of log k_obsd vs. pH for the di-n-propyl acetal, the 1,3-dioxolane, and the 1,3-oxathiolane are pH inde

Full text of DOI:10.1021/ja00269a048

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