Stereochemical Investigations of Samarium(II) Iodide-Promoted 5-Exo and 6-Exo Ketyl-Olefin Radical Cyclization Reactions

DOI: 10.1021/jo00109a018

Source and publish data:

Journal of Organic Chemistry p. 872 - 882 (1995)

Update date:2022-08-02

Topics:

Authors:

Molander, Gary A.

McKie, Jeffrey A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00109a018

Samarium(II) iodide (SmI2)-promoted ketyl cyclizations of several substituted, unsaturated ketones, providing various cyclpentyl and cyclohexyl systems, have been investigated.The resulting experiments provide stereochemical insight into these reactions and in addition outline the synthetic potential of these 5-exo and 6-exo radical cyclization processes.

Full text of DOI:10.1021/jo00109a018

Products guided by the article

Product name:Non-8-en-3-ol

Cas No:99389-77-2

R&D Labs maybe for 99389-77-2

Shanghai Pinewood Fine Chemical Co., Ltd.

website:http://www.pinewoodchem.com

Contact:0086-21-62417129，62414096

Address:Suite B, 27F, No.2, Lane 600, Tianshan Road, Shanghai
Kraeber & Co GmbH

Contact:+49-4101-3053-0

Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
Chengdu Sino-Strong Pharmaceutical Co.,Ltd.

website:http://www.sino-strong.com.cn

Contact:+86-28-82666753

Address:459 West haike road,Cross-straits technological industry park, Wenjiang district,Chengdu, P.R.China
Shanxi Tongji Pharmaceuticals Co., Ltd.

Contact:+86-359-3024784

Address:Xikuang South Road, Ruicheng County , Shanxi
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD(expird)

Contact:+86-311-85208698 311-80837698

Address:NO.166, yuhua west road, SHIJIAZHUANG, China

Relevant to this article

Easy access to 2-alkyl and 2-arylthiazolines using a modified heteropolyacid catalysis: Application to the synthesis of bacillamide A

Doi:10.1080/00397911.2011.552834
(2012)
Doi:10.1021/ja00794a015
(1973)
Improved synthesis of indirubin derivatives by sequential build-up of the indoxyl unit: First preparation of fluorescent indirubins

Doi:10.1002/hlca.201200042
(2012)
Doi:10.1055/s-1973-22291
(1973)
Complexing ability of the versatile, redox-active, 3-[3-(diphenylphosphino)propylthio]-3′,4,4′-trimethyl- tetrathiafulvalene ligand

Doi:10.1021/ic026186f
(2003)
N-sulfinyl beta-amino Weinreb amides: synthesis of enantiopure beta-amino carbonyl compounds. Asymmetric synthesis of (+)-sedridine and (-)-allosedridine.

Doi:10.1021/ol034119z
(2003)

Article Doi