Stereochemical Investigations of Samarium(II) Iodide-Promoted 5-Exo and 6-Exo Ketyl-Olefin Radical Cyclization Reactions

DOI: 10.1021/jo00109a018

Source and publish data:

Journal of Organic Chemistry p. 872 - 882 (1995)

Update date:2022-08-02

Topics:

Authors:

Molander, Gary A.

McKie, Jeffrey A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00109a018

Samarium(II) iodide (SmI2)-promoted ketyl cyclizations of several substituted, unsaturated ketones, providing various cyclpentyl and cyclohexyl systems, have been investigated.The resulting experiments provide stereochemical insight into these reactions and in addition outline the synthetic potential of these 5-exo and 6-exo radical cyclization processes.

Full text of DOI:10.1021/jo00109a018

Products guided by the article

Product name:Non-8-en-3-ol

Cas No:99389-77-2

R&D Labs maybe for 99389-77-2

SHAANXI FUJIE PHARMACEUTICAL CO.,LTD

website:http://www.fujiepharm.com

Contact:+86-29-63650906

Address:Yuanqu Yi Road, Qinghe Food Industrial Park, Sanyuan County, Shaanxi Province, China
shanghai Tauto Biotech Co., Ltd

website:http://www.tautobiotech.com/en/index.htm

Contact:+86-21-51320588 ext. 8025

Address:No. 326, Aidisheng Rd , Zhangjiang Hi-tech Park, Shanghai , P.R.CHINA
ChengduChroma-BiotechCo.,Ltd.

Contact:86-28-61993785

Address:No.70-13-21, North Section, Erhuan
Lonzeal Pharmaceuticals Co., Ltd.

website:http://www.lonzeal.com

Contact:+86-13381011962

Address:RM 801, Yue MOMA, No. 26 Anningzhuang Rd. Haidian District, Beijing, China
Hubei anhuang chemical Co.Ltd

Contact:

Address:308# dongwu avenue dongxihu district wuhan city

Relevant to this article

Easy access to 2-alkyl and 2-arylthiazolines using a modified heteropolyacid catalysis: Application to the synthesis of bacillamide A

Doi:10.1080/00397911.2011.552834
(2012)
Doi:10.1021/ja00794a015
(1973)
Improved synthesis of indirubin derivatives by sequential build-up of the indoxyl unit: First preparation of fluorescent indirubins

Doi:10.1002/hlca.201200042
(2012)
Doi:10.1055/s-1973-22291
(1973)
Complexing ability of the versatile, redox-active, 3-[3-(diphenylphosphino)propylthio]-3′,4,4′-trimethyl- tetrathiafulvalene ligand

Doi:10.1021/ic026186f
(2003)
N-sulfinyl beta-amino Weinreb amides: synthesis of enantiopure beta-amino carbonyl compounds. Asymmetric synthesis of (+)-sedridine and (-)-allosedridine.

Doi:10.1021/ol034119z
(2003)

Article Doi