Stereochemical Investigations of Samarium(II) Iodide-Promoted 5-Exo and 6-Exo Ketyl-Olefin Radical Cyclization Reactions

DOI: 10.1021/jo00109a018

Source and publish data:

Journal of Organic Chemistry p. 872 - 882 (1995)

Update date:2022-08-02

Topics:

Authors:

Molander, Gary A.

McKie, Jeffrey A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00109a018

Samarium(II) iodide (SmI2)-promoted ketyl cyclizations of several substituted, unsaturated ketones, providing various cyclpentyl and cyclohexyl systems, have been investigated.The resulting experiments provide stereochemical insight into these reactions and in addition outline the synthetic potential of these 5-exo and 6-exo radical cyclization processes.

Full text of DOI:10.1021/jo00109a018

Products guided by the article

Product name:Non-8-en-3-ol

Cas No:99389-77-2

R&D Labs maybe for 99389-77-2

TIANJIN DONGRUXIANG MINERALS MARKETING CO.,LTD(expird)

Contact:22-58516360

Address:tianjin
Liaoyang hengye Chemical Co., Ltd.

Contact:86-419-5850866

Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China
Zouping Mingxing Chemical Co.,Ltd.

website:http://www.zoutong.com.cn

Contact:86-543-2240068 2240067

Address:428 Daixi Third Road Zouping County Shandong Province China
Chongqing Shuangfeng Chemical Co.,Ltd

Contact:+86-23-49850156

Address:No.663,xuanhua Rd,yongchuan,chongqing,China
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China

Relevant to this article

Easy access to 2-alkyl and 2-arylthiazolines using a modified heteropolyacid catalysis: Application to the synthesis of bacillamide A

Doi:10.1080/00397911.2011.552834
(2012)
Doi:10.1021/ja00794a015
(1973)
Improved synthesis of indirubin derivatives by sequential build-up of the indoxyl unit: First preparation of fluorescent indirubins

Doi:10.1002/hlca.201200042
(2012)
Doi:10.1055/s-1973-22291
(1973)
Complexing ability of the versatile, redox-active, 3-[3-(diphenylphosphino)propylthio]-3′,4,4′-trimethyl- tetrathiafulvalene ligand

Doi:10.1021/ic026186f
(2003)
N-sulfinyl beta-amino Weinreb amides: synthesis of enantiopure beta-amino carbonyl compounds. Asymmetric synthesis of (+)-sedridine and (-)-allosedridine.

Doi:10.1021/ol034119z
(2003)

Article Doi