Stereochemical Investigations of Samarium(II) Iodide-Promoted 5-Exo and 6-Exo Ketyl-Olefin Radical Cyclization Reactions

DOI: 10.1021/jo00109a018

Source and publish data:

Journal of Organic Chemistry p. 872 - 882 (1995)

Update date:2022-08-02

Topics:

Authors:

Molander, Gary A.

McKie, Jeffrey A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00109a018

Samarium(II) iodide (SmI2)-promoted ketyl cyclizations of several substituted, unsaturated ketones, providing various cyclpentyl and cyclohexyl systems, have been investigated.The resulting experiments provide stereochemical insight into these reactions and in addition outline the synthetic potential of these 5-exo and 6-exo radical cyclization processes.

Full text of DOI:10.1021/jo00109a018

Products guided by the article

Product name:Non-8-en-3-ol

Cas No:99389-77-2

R&D Labs maybe for 99389-77-2

Jiaozuo Zhongwei Special Products Pharmaceutical Co.,Ltd.

website:http://www.zw-pvp.com

Contact:15302105619

Address:Jiaozuo,Henan,China (Mainland)
Nanjing distinctions Medical Technology Co., Ltd.(expird)

Contact:+86-15996203785 13914714059

Address:nanjing,jiangsu , China
Shandong LuZhou Amino Acid Co., Ltd

Contact:86-539-2218025

Address:yishui economic and technical development zone zhenxing south road
SINO Industries Company Limited(expird)

Contact:86-29-85369724

Address:No.111, Jiefang Road, Xi’an, China
Nanjing Vincero International Trading Co.,Ltd

Contact:8618936897229

Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703

Relevant to this article

Easy access to 2-alkyl and 2-arylthiazolines using a modified heteropolyacid catalysis: Application to the synthesis of bacillamide A

Doi:10.1080/00397911.2011.552834
(2012)
Doi:10.1021/ja00794a015
(1973)
Improved synthesis of indirubin derivatives by sequential build-up of the indoxyl unit: First preparation of fluorescent indirubins

Doi:10.1002/hlca.201200042
(2012)
Doi:10.1055/s-1973-22291
(1973)
Complexing ability of the versatile, redox-active, 3-[3-(diphenylphosphino)propylthio]-3′,4,4′-trimethyl- tetrathiafulvalene ligand

Doi:10.1021/ic026186f
(2003)
N-sulfinyl beta-amino Weinreb amides: synthesis of enantiopure beta-amino carbonyl compounds. Asymmetric synthesis of (+)-sedridine and (-)-allosedridine.

Doi:10.1021/ol034119z
(2003)

Article Doi