Stereochemical Investigations of Samarium(II) Iodide-Promoted 5-Exo and 6-Exo Ketyl-Olefin Radical Cyclization Reactions

DOI: 10.1021/jo00109a018

Source and publish data:

Journal of Organic Chemistry p. 872 - 882 (1995)

Update date:2022-08-02

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Authors:

Molander, Gary A.

McKie, Jeffrey A.

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Article abstract of DOI:10.1021/jo00109a018

Samarium(II) iodide (SmI2)-promoted ketyl cyclizations of several substituted, unsaturated ketones, providing various cyclpentyl and cyclohexyl systems, have been investigated.The resulting experiments provide stereochemical insight into these reactions and in addition outline the synthetic potential of these 5-exo and 6-exo radical cyclization processes.

Full text of DOI:10.1021/jo00109a018

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