UEBERGANGSMETALL-SUBSTITUIERTE PHOSPHANE, ARSANE UND STIBANE. XLVIII. BORIN-KOMPLEXE DER METALLO-PHOSPHANE Cp(CO)2(L)M-PPh2 (M=Mo, W; L=CO, Me3P)

Article abstract of DOI:10.1016/0022-328X(85)88016-5

The reaction of the metallophosphanes Cp(CO)2(L)M-PPh2 (1a-1c) (M=Mo, W; L=CO, Me3P) with H3B*THF yields the thermally stable borane adducts Cp(CO)2(L)-PPh2-BH3 (2a-2c), while with BF3*OEt2 the complex salts ;BF4 (3a-3c) are obtained.Th