A ONE-STEP TRANSFORMATION OF AROMATIC ALDEHYDES TO NITRILES, USING S,S-DIMETHYL SULFURDIIMIDE AS IMINATING AGENT. ISOLATION OF DITHIATETRAZOCINES AS REACTION INTERMEDIATES.

DOI: 10.1016/S0040-4039(00)94899-8

Source and publish data:

Tetrahedron Letters p. 2739 - 2742 (1985)

Update date:2022-08-03

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Authors:

Georg, Gunda I.

Pfeifer, Sarah A.

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Article abstract of DOI:10.1016/S0040-4039(00)94899-8

S;S-Dimethylsulfurdiimide is explored as a novel and effective reagent for the direct synthesis of aromatic nitriles from aldehydes.A novel eight-membered heterocycle is isolated as a reaction intermediate and a mechanism for this reaction is discussed.

Full text of DOI:10.1016/S0040-4039(00)94899-8

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