Phase-Transfer-Catalyzed Conversion of Alkynes to Lactones Induced by Manganase Carbonyl Complexes

DOI: 10.1021/jo00352a037

Source and publish data:

Journal of Organic Chemistry p. 273 - 275 (1986)

Update date:2022-07-31

Topics:

Authors:

Wang, Jin-Xian

Alper, Howard

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Article abstract of DOI:10.1021/jo00352a037

Alkynes react with methyl iodide, bromopentacarbonylmanganese (or dimanganese decacarbonyl), and carbon monoxide, under phase-transfer catalysis conditions, to give γ-butyrolactones; the reaction conditions are mild <35 deg C (1atm)>, and the process is a regiospecific one

Full text of DOI:10.1021/jo00352a037

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