Phase-Transfer-Catalyzed Conversion of Alkynes to Lactones Induced by Manganase Carbonyl Complexes

DOI: 10.1021/jo00352a037

Source and publish data:

Journal of Organic Chemistry p. 273 - 275 (1986)

Update date:2022-07-31

Topics:

Authors:

Wang, Jin-Xian

Alper, Howard

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00352a037

Alkynes react with methyl iodide, bromopentacarbonylmanganese (or dimanganese decacarbonyl), and carbon monoxide, under phase-transfer catalysis conditions, to give γ-butyrolactones; the reaction conditions are mild <35 deg C (1atm)>, and the process is a regiospecific one

Full text of DOI:10.1021/jo00352a037

Products guided by the article

Product name:4-methyl-2-(2-phenylethyl)-γ-butyrolactone

Cas No:99593-45-0

R&D Labs maybe for 99593-45-0

Tosta Enterprise Co., Ltd.

Contact:+86-134-5286-9121

Address:Add: Wing Tuck Commercial Centre, 177-183 Wing Lok Street, Hong Kong,
Anhui Xinyuan Technology Co.,Ltd

Contact:0086-559-3515800

Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
CHEM PLUS

Contact:0027-717-456976

Address:2ND FLOOR, 325 VAUSE ROAD, OVERPORT, 4001, SOUTH AFRICA
Shanghai Longjin Metallic Material Co., Ltd.

website:http://www.shlongjin.cn/

Contact:021-56517503,56502257

Address:No.16, Lane 555, Chengyin Road, Shanghai
Taizhou Chemedir Biopharm-tech Co., Ltd

Contact:+86 523 86200218

Address:G09, No. 1 Avenue China Medical City, Taizhou,Jiangsu, China

Relevant to this article

Enantioselective synthesis and vanilloid activity evaluation of 1-β-(p-methoxycinnamoyl)polygodial, an antinociceptive compound from Drymis winteri barks

Doi:10.1016/j.bmcl.2007.10.001
(2007)
Three-component synthesis and anticancer evaluation of polycyclic indenopyridines lead to the discovery of a novel indenoheterocycle with potent apoptosis inducing properties

Doi:10.1039/b713820b
(2007)
Gold(I) and bronsted acid catalyzed intramolecular rearrangements of vinylidenecyclopropanes

Doi:10.1002/chem.201001433
(2010)
The rational design of a novel potent analogue of the 5′-AMP- activated protein kinase inhibitor compound C with improved selectivity and cellular activity

Doi:10.1016/j.bmcl.2010.09.088
(2010)
Cleavage of an RNA model catalyzed by dinuclear Zn(II) complexes containing rate-accelerating pendants. Comparison of the catalytic benefits of H-bonding and hydrophobic substituents

Doi:10.1021/jo1017316
(2010)
Enhanced poling efficiency in rigid-flexible dendritic nonlinear optical chromophores

Doi:10.1007/s10847-010-9781-9
(2010)

Article Doi