CYCLISATION OF ALLYL SILANES. FORMAL TOTAL SYNTHESIS OF (+/-)-MESEMBRINE

DOI: 10.1016/S0040-4039(00)89298-9

Source and publish data:

Tetrahedron Letters p. 4083 - 4086 (1985)

Update date:2022-08-05

Topics:

Authors:

Gramain, Jean-Claude

Remuson, Roland

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)89298-9

The intramolecular reaction of an α-acyl iminium ion with an allyl silane occurs under non acidic conditions to afford the key intermediate 8 for the synthesis of (+/-)-mesembrine 1 in a stereospecific manner.

Full text of DOI:10.1016/S0040-4039(00)89298-9

Products guided by the article

Product name:N-methyl-3-(3,4-dimethoxyphenyl)-3-<3-(trimethylsilylmethyl)but-3-en-1-yl>succinimide

Cas No:99897-25-3

R&D Labs maybe for 99897-25-3

Laohekou Jinghong Chemical Co.,Ltd

Contact:+86-0710-3702747

Address:163.East，Huagong Road，Laohekou
Borun Chemical Co.,Ltd.

Contact:+86-574- 87178138; 87297407

Address:No. 809, Liudingxingzuo, cangsong road, Ningbo, China
Beijing Wisdom Chemicals Co., Ltd.

Contact:+86-10-52350335

Address:F2, BLDG 19, Liando Valley U, Majuqiao, Tongzhou District, Beijing, China
Shenzhen Feiming Science and Technology Co,. Ltd

Contact:+86-755-85232577

Address:#B2309, Fenglin International Center ,Jixiang Road, Longcheng street, LongGang District, Shenzhen city, Guangdong province, China.
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA

Relevant to this article

THE PREPARATION OF 4-SUBSTITUTED BENZOTHIADIAZINES.

Doi:10.1021/jm00336a040
(1964)
Doi:10.1016/S0040-4020(01)93323-X
(1960)
Group 4 metal complexes of fhiorous (Di)alkoxide-(Di)imino ligands: synthesis, structure, olefin polymerization catalysis, and decomposition pathways

Doi:10.1021/om8009409
(2009)
Chiral Chromium Salen@rGO as Multipurpose and Recyclable Heterogeneous Catalyst

Doi:10.1002/chem.202101003
(2021)
Reaction of Ethyl (E)-3-Methoxy-2-butenoate with Some Substituted Aromatic Aldehydes: Synthesis of 5-Aryl-3-Methoxy-(2E,4E)-2,4-Pentadienoic Acids

Doi:10.1055/s-1987-28038
(1987)
4-(4-Chloro-benzyl-idene-hydrazono-methyl)-benzonitrile and the bromo and iodo analogs

Doi:10.1107/S0108270107065171
(2008)

Article Doi