
Tetrahedron Letters p. 4083 - 4086 (1985)
Update date:2022-08-05
Topics:
Gramain, Jean-Claude
Remuson, Roland
The intramolecular reaction of an α-acyl iminium ion with an allyl silane occurs under non acidic conditions to afford the key intermediate 8 for the synthesis of (+/-)-mesembrine 1 in a stereospecific manner.
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