CYCLISATION OF ALLYL SILANES. FORMAL TOTAL SYNTHESIS OF (+/-)-MESEMBRINE

DOI: 10.1016/S0040-4039(00)89298-9

Source and publish data:

Tetrahedron Letters p. 4083 - 4086 (1985)

Update date:2022-08-05

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Authors:

Gramain, Jean-Claude

Remuson, Roland

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Article abstract of DOI:10.1016/S0040-4039(00)89298-9

The intramolecular reaction of an α-acyl iminium ion with an allyl silane occurs under non acidic conditions to afford the key intermediate 8 for the synthesis of (+/-)-mesembrine 1 in a stereospecific manner.

Full text of DOI:10.1016/S0040-4039(00)89298-9

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