(α-Ethoxyvinyl)tributyltin; An Efficient Reagent for the Nucleophilic Acetylation of Organic Halides via Palladium Catalysis

DOI: 10.1246/bcsj.60.767

Source and publish data:

Bulletin of the Chemical Society of Japan p. 767 - 768 (1987)

Update date:2022-08-28

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Authors:

Kosugi, Masanori

Sumiya, Takashi

Obara, Yukimasa

Suzuki, Motohiro

Sano, Hiroshi

Migita, Toshihiko

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Article abstract of DOI:10.1246/bcsj.60.767

(α-Ethoxyvinyl)tributyltin acts as a masked acetylating agent in the palladium catalyzed reaction with various organic halides, such as aryl bromides, vinyl bromides, benzyl chloride, and allyl chloride, giving, after hydrolysis of the resulting reaction mixture, good yields of the corresponding ketone product.

Full text of DOI:10.1246/bcsj.60.767

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