Semicarbazones and Thiosemicarbazones, XIII : Study of the Hydrolysis of Coordinated Thiosemicarbazones

Article abstract of DOI:10.1007/BF00810822

The hydrolysis of coordinated thiosemicarbazones was studied.It was found that the nickel(II)ion promotes the reaction.Steric and electronic influences were found.The hydrolysis of ATSC in the trigonal bipyramid compounds Cl , is higher with the Ni(II) complex, the compound with the shorter M-N distance. Keywords.Thiosemicarbazones; Hydrolysis; Reactivity.