Semicarbazones and Thiosemicarbazones, XIII : Study of the Hydrolysis of Coordinated Thiosemicarbazones

DOI: 10.1007/BF00810822

Source and publish data:

Monatshefte fur Chemie p. 235 - 240 (1991)

Update date:2022-08-11

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Authors:

Cabrera, Armando

Diaz-Tejeda, Alfonso

Marquez, Carmen

Valdes-Martinez, Jesus

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Article abstract of DOI:10.1007/BF00810822

The hydrolysis of coordinated thiosemicarbazones was studied.It was found that the nickel(II)ion promotes the reaction.Steric and electronic influences were found.The hydrolysis of ATSC in the trigonal bipyramid compounds Cl , is higher with the Ni(II) complex, the compound with the shorter M-N distance. Keywords.Thiosemicarbazones; Hydrolysis; Reactivity.

Full text of DOI:10.1007/BF00810822

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