C=C Double Bond Insertion in Catalytic C-H Activation. Dehydrogenative Cross Coupling of Arenes with Olefins

DOI: 10.1246/cl.1988.685

Source and publish data:

Chemistry Letters p. 685 - 688 (1988)

Update date:2022-08-17

Topics:

Authors:

Sasaki, Koushi

Sakakura, Toshiyasu

Tokunaga, Yuko

Wada, Keisuke

Tanaka, Masato

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Article abstract of DOI:10.1246/cl.1988.685

The reaction of benzene with methyl acrylate and ethylene catalyzed by RhCl(CO)(PMe3)2 under irradiation gave methyl cinnamate and styrene, respectively.The reaction of toluene afforded meta-substituted isomers as major products.

Full text of DOI:10.1246/cl.1988.685

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