Mercury in Organic Chemistry. 25. Rhodium(I)-Catalyzed Alkenylation of Arylmercurials

DOI: 10.1021/jo00171a044

Source and publish data:

Journal of Organic Chemistry p. 4377 - 4380 (1983)

Update date:2022-08-11

Topics:

Authors:

Larock, R. C.

Narayanan, K.

Hershberger, S. S.

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Article abstract of DOI:10.1021/jo00171a044

Arylmercurials and vinyl halides are catalytically cross-coupled to aryl olefins in fair to good yields by 10percent ClRh(PPh3)3.This reaction appears to proceed through an arylvinylrhodium(III) intermediate.

Full text of DOI:10.1021/jo00171a044

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