Efficient Reduction of Azides with Samarium Diiodide

DOI: 10.1016/0040-4039(95)80003-4

Source and publish data:

Tetrahedron Letters p. 7427 - 7430 (1995)

Update date:2022-08-29

Topics:

Authors:

Goulaouic-Dubois, Catherine

Hesse, Manfred

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Article abstract of DOI:10.1016/0040-4039(95)80003-4

Reduction of alkyl, aryl and aroyl azides to the parent primary amines or amides, respectively, occurs in good yield upon treatment with an excess of SmI2 in THF at room temperature.A radical mechanism is proposed.

Full text of DOI:10.1016/0040-4039(95)80003-4

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