High Deoxygenation Ability of Rh Carbonyl Clusters toward Oximes Leading to Nitrile Formation

DOI: 10.1246/cl.1988.285

Source and publish data:

Chemistry Letters p. 285 - 286 (1988)

Update date:2022-08-29

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Authors:

Kaneda, Kiyotomi

Doken, Kazuhiro

Imanaka, Toshinobu

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Article abstract of DOI:10.1246/cl.1988.285

Nitriles are selectively prepared by reaction of aldoximes with CO and H2O in the presence of rhodium carbonyl clusters.Rh₁₂ and Rh₁₃ carbonyl cluster anions can be detected by IR spectroscopy.

Full text of DOI:10.1246/cl.1988.285

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