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Studies on Transition-Metal Oxo and Nitrido Complexes. Part 10. New Oxo-Ruthenium and Oxo-Osmium Pyridine Complexes, and Use of the Former as Catalysts for Oxidation of Alcohols

DOI: 10.1039/DT9890000901

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 901 - 906 (1989)

Update date:2022-08-16

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Authors:

El-Hendawy, Ahmed M.El-Hendawy, Ahmed M.

Griffith, William P.Griffith, William P.

Taha, Fatma I.Taha, Fatma I.

Moussa, Mahmoud N.Moussa, Mahmoud N.

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Article abstract of DOI:10.1039/DT9890000901

The new complexes trans-(2+), trans-(2+), trans- (M=Ru or Os; X=Cl or Br; py= pyridine) and trans- are reported.Both tans-(2+) and trans- in CH2Cl2 are efficient oxidants for primary alcohols to aldehydes and secondary alcohols to ketones, and function catalytically, with N-methylmorpholine N-oxide (mmo) or n4> as co-oxidants.A simple preparation of trans- and the isolation of , , and OsO2L2(O2C6H10)> (L=pyridine N-oxide) are also reported. Complexes were characterised by Raman, i.r. and (1)H n.m.r.spectroscopy.

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