
Advanced Synthesis and Catalysis p. 574 - 578 (2012)
Update date:2022-08-17
Topics:
Zhao, Wenwen
Wu, Jingjing
Cao, Song
A simple and highly efficient approach for the hydrodefluorination of both fluoroarenes and trifluorotoluenes in the presence of lithium triethylborohydride using a catalytic amount of nickel(II) chloride (NiCl 2, 2 mol%) combined with a catalytic amount of bis(tricyclohexylphosphine)nickel(II) chloride [NiCl2(PCy 3)2, 2 mol%] as cocatalyst has been developed. Copyright
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