A novel, highly efficient and selective desilylating method for trialkylsilyl ethers

DOI: 10.1016/S0040-4039(98)01035-1

Source and publish data:

Tetrahedron Letters p. 5249 - 5252 (1998)

Update date:2022-08-17

Topics:

Authors:

Lee, Adam Shih-Yuan

Yeh, Hsiu-Chih

Shie, Jiun-Jie

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(98)01035-1

A series of tert-butyldimethylsilyl, tert-butyldiphenylsilyl and triisopropylsilyl ethers are hydrolyzed to theirs corresponding alcohols in CBr₄ / CH₃OH (0.1 eq. / 10mL) reaction system under refluxing condition. The chemoselectivity can be achieved between primary and secondary triisopropylsilyl ethers when more hindered 2-propanol is used instead of methanol.

Full text of DOI:10.1016/S0040-4039(98)01035-1

Products guided by the article

Product name:Benzyl alcohol

Cas No:100-51-6

R&D Labs maybe for 100-51-6

Hotechem Shanghai Co., Ltd

Contact:13120882795；+86-21-34621078;+86-021-31122318

Address:Suite 2,No.2715 Longwu Road
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
Dezhou Longteng Chemical Co., Ltd.

website:http://www.sodium-methoxide.cn/

Contact:0086-18866052283

Address:Xinhua Industrial Zone, Dezhou City, Shandong Province, China
Shanghai Biobond Pharmaceutical Co.,Ltd

website:http://www.sh-biobond.com/EnglishIndex.aspx

Contact:021-68719686 /18939786273/ 18917373795

Address:Shanghai Zhangjiang
zonk drug r&d limited

Contact:+86-20-32051076

Address:1105,Building A, International Business Incubator,Science City

Relevant to this article

N-O Bond Fission as the Rate-Determining Step in the Aqueous Conversion of N-Peptidyl-O-(p-nitrobenzoyl)hydroxylamines to p-Nitrobenzoic Acid and Peptidylhydroxamic Acids

Doi:10.1021/jo00286a017
(1989)
Enzymatic cleavage of the C-glucosidic bond of puerarin by three proteins, Mn²⁺, and oxidized form of nicotinamide adenine dinucleotide

Doi:10.1248/bpb.b12-01011
(2013)
The effect of the acidifying group on the regioselectivity of the base-induced ring opening of hetero-oxabicyclic [3.2.1] and [3.3.1] systems

Doi:10.1016/S0040-4039(98)00052-5
(1998)
Surfactant-assisted hydrothermal route to organometallic tris(8-hydroxyquinoline)aluminum nanorod bundles

Doi:10.1246/cl.2007.630
(2007)
Hydrosilylation of olefins catalyzed by well-Defined cationic aluminum complexes: Lewis acid versus insertion mechanisms

Doi:10.1021/acscatal.6b01694
(2016)
Double subroutine self-assembly; spontaneous generation of a nanocyclic dodecanuclear Cu(I) inorganic architecture

Doi:10.1002/chem.19970030116
(1997)

Article Doi