720
M.R. Maurya et al. / Polyhedron 31 (2012) 710–720
[12] M.H. Valkenberg, W.F. Holderich, Catal. Rev. 44 (2002) 321.
[13] D.E. De Vos, B.F. Sels, P.A. Jacobs, Adv. Synth. Catal. 345 (2003) 457.
[14] D.E. De Vos, M. Dams, B.F. Sels, P.A. Jacobs, Chem. Rev. 102 (2002) 3615.
[15] J. Poltowicz, K. Pamin, E. Tabor, J. Haber, A. Adamski, Z. Sojka, Appl. Catal. A:
Gen. 299 (2006) 235.
[16] S.P. Verkey, C. Ratnasamy, P. Ratnasamy, J. Mol. Catal. A: Chem. 135 (1998)
295.
[17] S.P. Verkey, C. Ratnasamy, P. Ratnasamy, Micropor. Mesopor. Mater. 22 (1998)
465.
[18] S.P. Verkey, C.R. Jacob, P. Ratnasamy, Appl. Catal. A: Gen. 182 (1999) 91.
[19] S. Deshpande, D. Srinivas, P. Ratnasamy, J. Catal. 188 (1999) 261.
[20] P. Das, I. Kúzniarska-Biernacka, A.R. Silva, A.P. Carvalho, J. Pires, C. Freire, J. Mol.
Catal. A: Chem. 248 (2006) 135.
[21] I. Kúzniarska-Biernacka, A.R. Silva, A.P. Carvalho, J. Pires, C. Freire, J. Mol. Catal.
A: Chem. 278 (2007) 82.
[22] H. Zhang, S. Xiang, J. Xiao, C. Li, J. Mol. Catal. A: Chem. 238 (2005) 175.
[23] M. Moghadam, S. Tangestaninejad, V. Mirkhani, I. Mohammadpoor-Baltork, M.
Moosavifar, J. Mol. Catal. A: Chem. 302 (2009) 68.
[24] I. Correia, J. Costa Pessoa, M.T. Duarte, R.T. Henriques, M.F.M. Piedade, L.F.
Veiros, T. Jackusch, A. Dornyei, T. Kiss, M.M.C.A. Castro, C.F.G.C. Geraldes, F.
Avecilla, Chem. Eur. J. 10 (2004) 2301.
respectively. Under the optimized conditions, a maximum of 76.9%
conversion of styrene by 4, 76.3% by 5 and 76.0% by 6 is obtained
with five major products namely styrene oxide , benzaldehyde, ben-
zoic acid, phenylacetaldehyde and 1-phenylethane-1,2-diol. Ben-
zoin gives ca. 93% conversion with three major products, benzyl,
benzoic acid and benzaldehyde-dimethylacetal. These complexes
are recyclable and heterogeneous in nature. Neat complexes have
comparable catalytic activity. Interaction of neat complexes with
H2O2 suggests the formation of oxidized active manganese interme-
diate species during catalytic reactions.
Acknowledgements
M.R.M. and P.S. are thankful to Council of Scientific and Indus-
trial Research (CSIR) New Delhi for financial assistance. C.H. also
acknowledges CSIR for NET – Junior/Senior Research fellowship.
[25] G.M. Sheldrick, SHELXL-97: An Integrated System for Solving and Refining
Crystal Structures from Diffraction Data (Revision 5.1), University of
Göttingen, Germany, 1997.
Appendix A. Supplementary data
[26] L. Sabater, C. Hureau, R. Guillot, A. Aukauloo, Inorg. Chem. 45 (2006) 2373.
[27] J. Lin, C. Tu, H. Lin, P. Jiang, J. Ding, Z. Guo, Inorg. Chem. Commun. 6 (2003) 262.
[28] M.R. Maurya, B. Singh, P. Adão, F. Avecilla, J. Costa Pessoa, Eur. J. Inorg. Chem.
(2007) 5720.
[29] T. Joseph, D. Srinivas, C.S. Gopinath, S.B. Halligudi, Catal. Lett. 83 (2002) 209.
[30] A. Syamal, M.R. Maurya, Indian J. Chem. 24A (1985) 836.
[31] H. Torayama, T. Nishide, H. Asada, M. Fujiwara, T. Matsushita, Polyhedron 17
(1998) 105.
[32] L.J. Boucher, V.W. Day, Inorg. Chem. 16 (1977) 1360.
[33] S.B. Kumar, S. Bhattacharyya, S.K. Dutta, E.T. Tiekink, M. Chaudhury, J. Chem.
Soc., Dalton Trans. (1995) 2619.
[34] S. Biswas, K. Mitra, C.H. Schwalbe, C.R. Lucas, S.K. Chattopadhyay, B. Adhikari,
Inorg. Chim. Acta 358 (2005) 2473.
CCDC 817986 and 817987 contain the supplementary crystallo-
graphic data for this paper. These data can be obtained free of
from the Cambridge Crystallographic Data Centre, 12 Union Road,
Cambridge CB2 1EZ, UK; fax: (+44) 1223 336 033; or e-mail: de-
posit@ccdc.cam.ac.uk. Supplementary data associated with this
article can be found, in the online version, at doi:10.1016/
[35] P.P. Knops-Gerrits, D.E. de Vos, P.A. Jacobs, J. Mol. Catal. A: Chem. 117 (1997)
57.
References
[36] K. Srinivasan, S. Perrier, J.K. Kochi, J. Mol. Catal. 36 (1986) 297.
[37] I. Fernandez, N. Khair, Chem. Rev. 103 (2003) 3651.
[38] F.M. Collins, A.R. Lucy, C. Sharp, J. Mol. Catal. A: Chem. 117 (1997) 397.
[39] I.V. Babich, J.A. Moulijn, Fuel 82 (2003) 607.
[40] X.M. Feng, Z. Wang, N.S. Bian, Z.L. Wang, Inorg. Chim. Acta 360 (2007) 4103.
[41] M.R. Maurya, P. Saini, A. Kumar, J. Costa Pessoa, Eur. J. Inorg. Chem. (2011)
4846.
[42] M.R. Maurya, A.K. Chandrakar, S. Chand, J. Mol. Catal. A: Chem. 270 (2007) 225.
[43] M. Silva, C. Freire, B. de Castro, J.L. Figueiredo, J. Mol. Catal. A: Chem. 258
(2006) 327.
[44] V. Hulea, E. Dumitriu, Appl. Catal. A Gen. 277 (2004) 99.
[45] S.B. Halligudi, N.K. Kalaraj, S.S. Deshpande, S. Gopinathan, J. Mol. Catal. A:
Chem. 157 (2000) 9.
[1] N.A. Law, M.T. Caudle, V.L. Pecoraro, Adv. Inorg. Chem. 46 (1998) 305.
[2] H. Sigel, A. Sigel, in: H. Sigel, A. Sigel (Eds.), Metal Ions in Biological Systems,
Marcel Dekker, Inc., 2000.
[3] G.C. Dismukes, Chem. Rev. 96 (1996) 2909.
[4] M.S. Lah, M.M. Dixon, K.A. Pattridge, W.C. Stallings, J.A. Fee, M.L. Ludwig,
Biochemistry 34 (1995) 1646.
[5] J.E. Penner-Hahn, in: H.A.O. Hill, P.J. Sadler, A.J. Thomson (Eds.), Metal Sites in
Proteins and Models, Springer-Verlag, 1998, p. 1.
[6] J. Limburg, V.A. Szalai, G.W. Brudvig, J. Chem. Soc., Dalton Trans. (1999) 1353.
[7] V.K. Yachandra, V.J. DeRose, M.J. Latimer, I. Mukerji, K. Sauer, M.P. Klein,
Science 260 (1993) 675.
[8] M. Sundaramoorthy, K. Kishi, M.H. Gold, T.L. Poulos, J. Biol. Chem. 269 (1994)
32759.
[9] L. Canali, D.C. Sherrington, Chem. Soc. Rev. 28 (1999) 85.
[10] M. Maneiro, M.R. Bermejo, M.I. Fernández, E. Gómez-Fórneas, A.M. González-
Noya, A.M. Tyryshkin, New J. Chem. 27 (2003) 727.
[46] M.R. Maurya, U. Kumar, P. Manikandan, Dalton Trans. (2006) 3561.
[47] M.R. Maurya, U. Kumar, P. Manikandan, Eur. J. Inorg. Chem. (2007) 2303.
[48] G.B. Gill, in: G. Pattenden (Ed.), Comprehensive Organic Synthesis, vol. 3,
Pergamon Press, New York, 1991, pp. 821–838.
[11] N.A.W.F. Holderich, F. Kollmer, Pure Appl. Chem. 72 (2000) 1273.