A NOVEL BASE-CATALYZED TRANSFORMATION OF α-AZOBENZYL HYDROPEROXIDE INTO BENZOIC ACID. A POSTULATED OXENOID INTERMEDIATE OF THE REACTION.

DOI: 10.1016/S0040-4039(00)88108-3

Source and publish data:

Tetrahedron Letters p. 3109 - 3112 (1983)

Update date:2022-08-11

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Authors:

Tezuka, T.

Iwaki, M.

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Article abstract of DOI:10.1016/S0040-4039(00)88108-3

α-Azobenzyl hydroperoxide (1) gives benzoic acid, 4-bromophenyl-pyridines (2 and 3) in addition to benzoyldiazene (4) and benzohydrazide (5) in the reaction catalyzed by pyridine; dioxirane (9) or carbonyl oxide (10) is proposed as an intermediate.

Full text of DOI:10.1016/S0040-4039(00)88108-3

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Product name:Benzaldehyde

Cas No:100-52-7

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Article Doi

A NOVEL BASE-CATALYZED TRANSFORMATION OF α-AZOBENZYL HYDROPEROXIDE INTO BENZOIC ACID. A POSTULATED OXENOID INTERMEDIATE OF THE REACTION.

DOI: 10.1016/S0040-4039(00)88108-3

Source and publish data:

Authors:

Article abstract of DOI:10.1016/S0040-4039(00)88108-3

Full text of DOI:10.1016/S0040-4039(00)88108-3

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