Oxidation of Hydrazine Derivatives with Arylsulfonyl Peroxides

DOI: 10.1021/jo00195a028

Source and publish data:

Journal of Organic Chemistry p. 4014 - 4017 (1984)

Update date:2022-08-11

Topics:

Authors:

Hoffman, Robert V.

Kumar, Anil

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Article abstract of DOI:10.1021/jo00195a028

A new method for the generation of the azo function is reported.A series of hydrazine derivatives, which included alkyl- and arylhydrazines, monoacylhydrazides, and diacylhydrazides, was oxidized with m-(trifluoromethyl)benzenesulfonyl peroxide.Smooth conversion to the diimide was observed.The diimides then yielded products typical of normal degradation pathways.

Full text of DOI:10.1021/jo00195a028

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