Tetrahedron Letters p. 7997 - 8000 (1992)
Update date:2022-08-31
Topics:
Chan, T. H.
Labrecque, D.
α-Silylallyl anions of the type 6 react with carbonyl compounds at the γ-position, and stereoselectively to give the E- or Z-isomer depending on the reaction conditions.Solvent and reaction temperature play a critical role in the control of stereoselectivity.
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