Journal of the Chemical Society. Chemical communications p. 2007 - 2008 (1995)
Update date:2022-08-29
Topics:
Fung, Wai-Hong
Cheng, Wing-Chi
Yu, Wing-Yiu
Che, Chi-Ming
Mak, Thomas C. W.
A new chiral monooxoruthenium(IV) complex containing 2,6-bis<(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl>pyridine and 2,2'-bipyridine ligands is prepared and the X-ray crystal structure of its RuII-OH2 precursor determined; this RuIV=O complex catalyses epoxidation of unfunctionalized alkenes with promising enantioselectivity.
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(1944)
