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Enantioselective Epoxidation of Unfunctionalized Alkenes by a Chiral Monooxoruthenium(IV) Complex 2+ pyridine; bpy = 2,2'-bipyridine>

DOI: 10.1039/c39950002007

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 2007 - 2008 (1995)

Update date:2022-08-29

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Authors:

Fung, Wai-HongFung, Wai-Hong

Cheng, Wing-ChiCheng, Wing-Chi

Yu, Wing-YiuYu, Wing-Yiu

Che, Chi-MingChe, Chi-Ming

Mak, Thomas C. W.Mak, Thomas C. W.

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Article abstract of DOI:10.1039/c39950002007

A new chiral monooxoruthenium(IV) complex containing 2,6-bis<(4S,7R)-7,8,8-trimethyl-4,5,6,7-tetrahydro-4,7-methanoindazol-2-yl>pyridine and 2,2'-bipyridine ligands is prepared and the X-ray crystal structure of its RuII-OH2 precursor determined; this RuIV=O complex catalyses epoxidation of unfunctionalized alkenes with promising enantioselectivity.

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Cas No:100-52-7

100-52-7

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